{"id":1298,"date":"2017-05-16T11:38:38","date_gmt":"2017-05-16T03:38:38","guid":{"rendered":"https:\/\/www.cililun.com\/?p=1298"},"modified":"2017-05-16T21:44:02","modified_gmt":"2017-05-16T13:44:02","slug":"shang_hai_gui_suan_yan_suo_zai_xi_tu_shang_zhuan_h","status":"publish","type":"post","link":"https:\/\/www.cililun.com\/shang_hai_gui_suan_yan_suo_zai_xi_tu_shang_zhuan_h\/","title":{"rendered":"\u4e0a\u6d77\u7845\u9178\u76d0\u6240\u5728\u7a00\u571f\u4e0a\u8f6c\u6362\u6750\u6599\u7528\u4e8e\u4e4f\u6c27\u80bf\u7624\u7684\u9ad8\u6548\u7cbe\u51c6\u6cbb\u7597\u4e2d\u53d6\u5f97\u7cfb\u5217\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"
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 \u4f17\u6240\u5468\u77e5\uff0c\u6076\u6027\u80bf\u7624\u4e25\u91cd\u5371\u5bb3\u4eba\u7c7b\u751f\u547d\u5065\u5eb7\uff0c\u5176\u4e2d\uff0c\u5b9e\u4f53\u80bf\u7624\u5360\u4e34\u5e8a\u6076\u6027\u80bf\u762485%\u4ee5\u4e0a\uff0c\u800c\u4e4f\u6c27\u662f\u5b9e\u4f53\u80bf\u7624\u7684\u91cd\u8981\u7279\u5f81\u4e4b\u4e00\u3002\u7531\u4e8e\u80bf\u7624\u4e4f\u6c27\u533a\u7684\u5b58\u5728\uff0c\u964d\u4f4e\u4e86\u80bf\u7624\u5bf9\u653e\u7597\u3001\u5316\u7597\u7684\u654f\u611f\u6027\uff0c\u5bfc\u81f4\u80bf\u7624\u65b0\u751f\u8840\u7ba1\u53ca\u4e4f\u6c27\u8bf1\u5bfc\u56e0\u5b50\u7684\u5f62\u6210\uff0c\u8bf1\u53d1\u80bf\u7624\u7ec6\u80de\u7684\u590d\u53d1\u3001\u4fb5\u88ad\u548c\u8f6c\u79fb\uff0c\u6210\u4e3a\u80bf\u7624\u96be\u4ee5\u6cbb\u6108\u7684\u6839\u672c\u539f\u56e0\u3002\u56e0\u6b64\uff0c\u9488\u5bf9\u4e4f\u6c27\u80bf\u7624\u7684\u9ad8\u6548\u6cbb\u7597\u662f\u56fd\u9645\u533b\u5b66\u754c\u516c\u8ba4\u7684\u5b9e\u73b0\u80bf\u7624\u5f7b\u5e95\u6cbb\u6108\u5fc5\u987b\u514b\u670d\u7684\u91cd\u8981\u96be\u9898\u3002 <\/p>\n
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\u3000\u3000\u4e2d\u56fd<\/a>\u79d1\u5b66<\/a>\u9662\u4e0a\u6d77<\/a>\u7845\u9178\u76d0\u7814\u7a76\u6240\u65bd\u5251\u6797\u7814\u7a76\u5458\u3001\u6b65\u6587\u535a\u7814\u7a76\u5458\u5e26\u9886\u7684\u7814\u7a76\u56e2\u961f\uff0c\u5728\u7a0d\u65e9\u671f\u7684\u7814\u7a76\u5de5\u4f5c\u4e2d\u5df2\u6210\u529f\u5b9e\u73b0\u4e86\u9ad8\u7075\u654f\u6c27\u611f\u5e94\u63a2\u9488\u5b9e\u65f6\u76d1\u63a7\u4e4f\u6c27\u80bf\u7624\u533a\u6c27\u5408\u72b6\u6001\uff08J. Am. Chem. Soc., 2014, 136 (27), 9701–9709.\uff09\uff0c\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u6700\u8fd1\u4ed6\u4eec\u501f\u52a9\u4e8e\u5316\u5b66\u7ec4\u5206\u8c03\u63a7\u548c\u5fae\u7ed3\u6784\u529f\u80fd\u5316\u8bbe\u8ba1\uff0c\u63d0\u51fa\u4e86“\u514b\u670d\u4e4f\u6c27”\u3001“\u5229\u7528\u4e4f\u6c27”\u548c“\u89c4\u907f\u4e4f\u6c27”\u4e09\u79cd\u5168\u65b0\u7684\u4e4f\u6c27\u80bf\u7624\u6cbb\u7597\u7b56\u7565\uff0c\u5728\u65b0\u578b\u591a\u529f\u80fd\u7a00\u571f<\/a>\u7eb3\u7c73\u8bca\u7597\u5242\u7528\u4e8e\u4e4f\u6c27\u80bf\u7624\u7684\u9ad8\u6548\u7cbe\u51c6\u6cbb\u7597\u4e2d\u53d6\u5f97\u4e86\u7cfb\u5217\u91cd\u8981\u521b\u65b0\u8fdb\u5c55\u3002 <\/div>\n
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\u3000\u3000\u9996\u5148\uff0c\u57fa\u4e8e“\u514b\u670d\u4e4f\u6c27”\u7684\u6cbb\u7597\u7b56\u7565\uff0c\u4ed6\u4eec\u8bbe\u8ba1\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u590d\u5408\u7ed3\u6784\u7a00\u571f<\/a>\u7eb3\u7c73\u8bca\u7597\u5242\uff08\u5982\u56fe1\u6240\u793a\uff09\uff0c\u5373\u5229\u7528\u8d1f\u8f7d\u4e0a\u8f6c\u6362\u7eb3\u7c73\u8bca\u7597\u5242\uff08UCSs\uff09\u7684MnO2\u7eb3\u7c73\u7247\u5c42\uff08UCSMs\uff09\uff0c\u53ef\u4ee5\u540c\u65f6\u5b9e\u73b0\u4e4f\u6c27\u54cd\u5e94\u578b\u4e0a\u8f6c\u6362\u53d1\u5149\uff08UCL\uff09\u6210\u50cf\u548c\u6c27\u589e\u5f3a\u578b\u5149\u52a8\u529b\u5b66\u6cbb\u7597\uff08PDT\uff09\/\u653e\u7597\u534f\u540c\u6cbb\u7597\u3002\u8be5\u7ed3\u6784\u8bbe\u8ba1\u4e0d\u4ec5\u53ef\u4ee5\u501f\u52a9\u4e8eUCSMs\u4e2d\u9ed1\u8272MnO2\u4e0e\u4e4f\u6c27\u5b9e\u4f53\u7624\u5185\u9178\u6027H2O2\u8fd8\u539f\u6210\u65e0\u8272Mn2+\uff0c\u6062\u590d\u88abMnO2\u6dec\u706d\u7684UCSs\u7684\u53d1\u5149\u4fe1\u53f7\uff0c\u5b9e\u73b0\u9ad8\u7075\u654fUCL\u6210\u50cf\uff0c\u7528\u4e8e\u7cbe\u786e\u5b9a\u4f4d\u4e4f\u6c27\u80bf\u7624\u7684\u4f4d\u7f6e\uff1b\u540c\u65f6\uff0c\u5229\u7528MnO2\u4e0e\u9178\u6027H2O2\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\uff0c\u53ef\u4ee5\u4ea7\u751f\u5927\u91cf\u7684O2\uff0c\u6709\u6548\u63d0\u9ad8\u4e4f\u6c27\u533a\u7684\u6c27\u5206\u538b\uff0c\u663e\u8457\u589e\u5f3a\u5149\u52a8\u529b\u5b66\u6cbb\u7597\u548c\u653e\u7597\u5bf9\u4e4f\u6c27\u5b9e\u4f53\u7624\u7684\u534f\u540c\u6740\u4f24\u4f5c\u7528\uff0c\u4ece\u800c\u8fbe\u5230\u6291\u5236\u4e4f\u6c27\u5b9e\u4f53\u7624\u7684\u751f\u957f\u3001\u4fb5\u88ad\u548c\u8f6c\u79fb\u7684\u76ee\u7684\uff08Adv. Mater., 2015, 27, 4155–4161\uff09\u3002 <\/div>\n
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\u3000\u3000\u5176\u6b21\uff0c\u57fa\u4e8e“\u5229\u7528\u4e4f\u6c27”\u7684\u6cbb\u7597\u7b56\u7565\uff0c\u4ed6\u4eec\u8bbe\u8ba1\u4e86\u4e00\u79cd\u57fa\u4e8e\u4e0a\u8f6c\u6362\u53d1\u5149\u63a2\u9488\u3001\u5149\u654f\u5242\u5206\u5b50\u548c\u751f\u7269\u8fd8\u539f\u6027\u836f\u7269\u5171\u62c5\u8f7d\u7684\u65b0\u578b\u591a\u529f\u80fd\u7eb3\u7c73\u8bca\u7597\u4f53\u7cfb\uff08\u5982\u56fe2\u6240\u793a\uff09\uff0c\u5b9e\u73b0\u4e86\u52a8\u529b\u5b66\u6cbb\u7597\uff08PDT\uff09\/\u5316\u7597\uff08\u5373\u751f\u7269\u8fd8\u539f\u6027\u6cbb\u7597\uff09\u9ad8\u6548\u534f\u540c\u6cbb\u7597\u3002\u8be5\u7ed3\u6784\u8bbe\u8ba1\u7684\u521b\u65b0\u601d\u8def\u662f\u501f\u52a9\u4e8e\u5149\u52a8\u529b\u5b66\u6cbb\u7597\u6280\u672f<\/a>\u8017\u6c27\u7684\u7279\u70b9\uff0c\u5e76\u5229\u7528\u7531\u6b64\u6240\u4ea7\u751f\u7684\u4e4f\u6c27\u5fae\u73af\u5883\uff0c\u534f\u540c\u589e\u5f3a\u751f\u7269\u8fd8\u539f\u836f\u7269\u5bf9\u4e4f\u6c27\u80bf\u7624\u7684\u6740\u4f24\u529b\uff1b\u5373\u501f\u52a9\u4e8e\u9ad8\u7ec4\u7ec7\u7a7f\u900f\u6df1\u5ea6\u7684\u8fd1\u7ea2\u5916\u6fc0\u53d1\u5149\uff0c\u6fc0\u53d1\u63a2\u9488\u53d1\u51fa\u7d2b\u5916\u5149\u548c\u53ef\u89c1\u5149\uff0c\u7528\u4e8e\u6fc0\u6d3b\u5149\u654f\u5242\u5206\u5b50\uff0cPDT\u4ea7\u751f\u76841O2\u53ef\u4ee5\u7834\u574f\u80bf\u7624\u5fae\u8840\u7ba1\uff0c\u52a0\u5267\u80bf\u7624\u7ec6\u80de\u5fae\u73af\u5883\u4e4f\u6c27\u7a0b\u5ea6\uff0c\u8fdb\u800c\u663e\u8457\u63d0\u5347\u751f\u7269\u8fd8\u539f\u836f\u7269\u7684\u6297\u764c\u6548\u679c\uff0c\u6700\u7ec8\u8fbe\u5230\u9ad8\u6548\u6cbb\u7597\u5b9e\u4f53\u80bf\u7624\u7684\u76ee\u7684\u3002\u6d3b\u4f53\u52a8\u7269\u5b9e\u9a8c\u8bc1\u5b9e\uff0c\u57fa\u4e8e\u5149\u52a8\u529b\u5b66\u6cbb\u7597\u548c\u751f\u7269\u8fd8\u539f\u6027\u836f\u7269\u7684\u534f\u540c\u6cbb\u7597\u7684\u6548\u679c\uff0c\u660e\u663e\u4f18\u4e8e\u4efb\u4f55\u4e00\u79cd\u5355\u4e00\u6cbb\u7597\u6a21\u5f0f\u6216\u4e24\u79cd\u6cbb\u7597\u6a21\u5f0f\u7b80\u5355\u52a0\u548c\u7684\u6548\u679c\uff0c\u4f53\u73b0\u4e86\u534f\u540c\u6cbb\u7597\u5728\u9ad8\u6548\u6cbb\u7597\u4e4f\u6c27\u5b9e\u4f53\u80bf\u7624\u4e2d\u7684\u663e\u8457\u4f18\u52bf (Angew. Chem. Int. Ed.,. 2015, 54, 8105–8109\uff09\u3002 <\/div>\n
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 <\/div>\n
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