{"id":2934,"date":"2017-03-31T01:08:30","date_gmt":"2017-03-30T17:08:30","guid":{"rendered":"https:\/\/www.cililun.com\/?p=2934"},"modified":"2017-03-31T01:16:15","modified_gmt":"2017-03-30T17:16:15","slug":"shang_hai_you_ji_suo_xi_tu_jin_shu_he_zhu_zu_yuan","status":"publish","type":"post","link":"https:\/\/www.cililun.com\/shang_hai_you_ji_suo_xi_tu_jin_shu_he_zhu_zu_yuan\/","title":{"rendered":"\u4e0a\u6d77\u6709\u673a\u6240\uff1a\u7a00\u571f\u91d1\u5c5e\u548c\u4e3b\u65cf\u5143\u7d20\u6c2e\u53cc\u952e\u7684\u5f62\u6210\u83b7\u8fdb\u5c55"},"content":{"rendered":"<div>\n<div>&nbsp; &nbsp; &nbsp;&nbsp;<span style=\"font-family: \u5b8b\u4f53; line-height: 25px; \">\u542b\u7279\u5f81M=N\u53cc\u952e\u7684\u524d\u8fc7\u6e21\u91d1\u5c5e\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u91d1\u5c5e\u914d\u5408\u7269\u3002\u4e00\u4e9b\u56fd\u9645\u77e5\u540d\u7684\u91d1\u5c5e\u6709\u673a\u5316\u5b66\u5bb6\uff0c\u5982\u7f8e\u56fd\u52a0\u5dde\u5927\u5b66\u4f2f\u514b\u5229\u5206\u6821\u7684R. G. Bergman\u548c\u9ebb\u7701\u7406\u5de5\u5b66\u9662\u7684R. R. Schrock\u7b49\uff0c\u6295\u8eab\u4e8e\u7b2cIVB\u65cf\u548c\u7b2cVB\u65cf\u91d1\u5c5e\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\u7684\u7814\u7a76\uff0c\u5e76\u53d6\u5f97\u4e86\u91cd\u8981\u8fdb\u5c55\u3002\u7136\u800c\uff0c\u91d1\u5c5e\uff08\u7b2cIIIB\u65cf\uff09\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\u5374\u4e00\u76f4\u7f3a\u5931\u3002\u8fd9\u662f\u7531\u4e8e\u76f8\u6bd4\u4e8e\u7b2cIVB\u65cf\u548c\u7b2cVB\u65cf\u7684\u91d1\u5c5e\u79bb\u5b50\uff0c<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u79bb\u5b50\u7684d\u8f68\u9053\u80fd\u7ea7\u548c\u6c2e\u5361\u5bbe\u7684p\u8f68\u9053\u80fd\u7ea7\u5339\u914d\u6027\u5dee\uff0c\u4f7f\u5f97<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e=\u6c2e\u53cc\u952e\u5f88\u4e0d\u7a33\u5b9a\uff0c<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\u9ad8\u5ea6\u6d3b\u6cfc\u3002 <\/p>\n<div style=\"text-align: center; \"><img loading=\"lazy\" decoding=\"async\" width=\"384\" height=\"277\" src=\"http:\/\/www.cnree.com\/skin\/default\/image\/lazy.gif\" original=\"http:\/\/www.cnree.com\/file\/upload\/201110\/09\/17-21-13-16-1.jpg\" alt=\"\u4e0a\u6d77\u6709\u673a\u6240\uff1a\u7a00\u571f\u91d1\u5c5e\u548c\u4e3b\u65cf\u5143\u7d20\u6c2e\u53cc\u952e\u7684\u5f62\u6210\u83b7\u8fdb\u5c55\" \/><\/div>\n<div style=\"text-align: center; \"><img loading=\"lazy\" decoding=\"async\" width=\"500\" height=\"317\" src=\"http:\/\/www.cnree.com\/skin\/default\/image\/lazy.gif\" original=\"http:\/\/www.cnree.com\/file\/upload\/201110\/09\/17-20-24-93-1.jpg\" alt=\"\u4e0a\u6d77\u6709\u673a\u6240\uff1a\u7a00\u571f\u91d1\u5c5e\u548c\u4e3b\u65cf\u5143\u7d20\u6c2e\u53cc\u952e\u7684\u5f62\u6210\u83b7\u8fdb\u5c55\" \/><\/div>\n<p> &nbsp; &nbsp;&nbsp;\u4e2d\u79d1\u9662<a href=\"https:\/\/www.cililun.com\/tag\/shang-hai\" title=\"\u4e0a\u6d77\" target=\"_blank\">\u4e0a\u6d77<\/a>\u6709\u673a\u5316\u5b66\u7814\u7a76\u6240\u91d1\u5c5e\u6709\u673a\u56fd\u5bb6\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u9648\u8000\u5cf0\u8bfe\u9898\u7ec4\u57fa\u4e8e\u6709\u673a\u914d\u4f53\u7684\u7535\u5b50\u6548\u5e94\u548c\u7acb\u4f53\u6548\u5e94\uff0c\u9488\u5bf9<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u79bb\u5b50\u786c\u9178\u3001\u5927\u79bb\u5b50\u534a\u5f84\u548c\u9ad8\u914d\u4f4d\u6570\u7684\u7279\u6027\uff0c\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u7c7b\u65b0\u578b\u7684\u4e09\u9f7f\u6c2e\u914d\u4f53\uff0c\u5e76\u901a\u8fc7\u5408\u6210\u5176<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u70f7\u57fa\u914d\u5408\u7269\uff0c\u9a8c\u8bc1\u5176\u786e\u5b9e\u5177\u6709\u4f18\u8d8a\u7684\u7535\u5b50\u6548\u5e94\u548c\u7acb\u4f53\u6548\u5e94\u7279\u6027(Organometallics 2008, 27, 758)\u3002 <\/p>\n<p style=\"list-style-type: none; list-style-position: initial; list-style-image: initial; margin-top: 12px; margin-right: 0px; margin-bottom: 12px; margin-left: 0px; padding-top: 0px; padding-right: 0px; padding-bottom: 0px; padding-left: 0px; line-height: 25px; \">&nbsp;\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528\u8be5\u7c7b\u914d\u4f53\uff0c\u5728\u5916\u52a0Lewis\u78b1DMAP\u7684\u914d\u5408\u4e0b\uff0c\u6210\u529f\u5730\u5408\u6210\u4e86\u7b2c\u4e00\u4f8b<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269-\u94aa\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\uff08\u56fe1\uff0cA\uff09\uff0c\u5e76\u5bf9\u8fd9\u4e2a\u914d\u5408\u7269\u8fdb\u884c\u4e86X-\u5c04\u7ebf\u6676\u4f53\u7ed3\u6784\u7684\u8868\u5f81\u548cDFT\u7406\u8bba\u8ba1\u7b97\u3002\u6709\u5173\u7ed3\u679c\u4ee5\u5c01\u9762\u6587\u7ae0\u7684\u5f62\u5f0f\u53d1\u8868\u5728(Chem. Commun., 2010, 46, 4469)\u3002\u8fdb\u800c\u53c8\u8bbe\u8ba1\u4e86\u4e00\u4e2a\u65b0\u578b\u7684\u56db\u9f7f\u6c2e\u914d\u4f53\uff0c\u65e0\u9700\u5916\u52a0Lewis\u78b1\u5c31\u53ef\u4ee5\u5f97\u5230<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u94aa\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\uff08\u56fe1\uff0cB\uff09\u3002<\/p>\n<p style=\"list-style-type: none; list-style-position: initial; list-style-image: initial; margin-top: 12px; margin-right: 0px; margin-bottom: 12px; margin-left: 0px; padding-top: 0px; padding-right: 0px; padding-bottom: 0px; padding-left: 0px; line-height: 25px; \">&nbsp;\u521d\u6b65\u53cd\u5e94\u6027\u80fd\u7814\u7a76\u53d1\u73b0\uff0c<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u94aa\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\u53ef\u4ee5\u6d3b\u5316\u5143\u7d20\u7852\u3001\u4e8c\u6c27\u5316\u78b3\u4ee5\u53ca\u82ef\u57fa\u6c30\u3001\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f\u3001\u5f02\u6c30\u9178\u3001\u73af\u6c27\u4e19\u70f7\u7b49\u6709\u673a\u5c0f\u5206\u5b50\uff0c\u663e\u793a\u5176\u4e30\u5bcc\u7684\u53cd\u5e94\u6027\u80fd (Chem. Commun., 2011, 47, 743; Angew. Chem. Int. Ed. 2011, 59, 7677)\u3002<\/p>\n<p style=\"list-style-type: none; list-style-position: initial; list-style-image: initial; margin-top: 12px; margin-right: 0px; margin-bottom: 12px; margin-left: 0px; padding-top: 0px; padding-right: 0px; padding-bottom: 0px; padding-left: 0px; line-height: 25px; \">&nbsp;\u8be5\u5de5\u4f5c\u63ed\u793a\u901a\u8fc7\u5408\u9002\u7684\u914d\u4f53\u8bbe\u8ba1\uff0c\u53ef\u4ee5\u5408\u6210\u548c\u7a33\u5b9a\u542b\u7279\u5f81<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u548c\u4e3b\u65cf\u5143\u7d20\u53cc\u952e\u7684\u91d1\u5c5e\u914d\u5408\u7269\uff0c\u4e3a\u5408\u6210\u542b<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\" title=\"\u7a00\u571f\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e\u548c\u5176\u5b83\u4e3b\u65cf\u5143\u7d20\uff08C,P\u7b49\uff09\u53cc\u952e\u7684\u91d1\u5c5e\u914d\u5408\u7269\u63d0\u4f9b\u4e86\u601d\u8def\uff0c\u5bf9\u5176\u53cd\u5e94\u6027\u80fd\u7684\u7814\u7a76\u4e5f\u63ed\u793a\u51fa<a href=\"https:\/\/www.cililun.com\/tag\/xi-tu\/\" title=\"\u70b9\u51fb\u4e86\u89e3\u66f4\u591a\u5173\u4e8e[\u7a00\u571f]\u7684\u6587\u7ae0\" target=\"_blank\">\u7a00\u571f<\/a>\u91d1\u5c5e=\u6c2e\u53cc\u952e\u72ec\u7279\u7684\u6027\u8d28\u3002<\/p>\n<p style=\"list-style-type: none; list-style-position: initial; list-style-image: initial; margin-top: 12px; margin-right: 0px; margin-bottom: 12px; margin-left: 0px; padding-top: 0px; padding-right: 0px; padding-bottom: 0px; padding-left: 0px; line-height: 25px; \">&nbsp;<\/p>\n<p style=\"list-style-type: none; list-style-position: initial; list-style-image: initial; margin-top: 12px; margin-right: 0px; margin-bottom: 12px; margin-left: 0px; padding-top: 0px; padding-right: 0px; padding-bottom: 0px; padding-left: 0px; line-height: 25px; \">&nbsp;\u8be5\u9879\u5de5\u4f5c\u5f97\u5230\u56fd\u5bb6\u81ea\u7136<a href=\"https:\/\/www.cililun.com\/tag\/ke-xue\/\" title=\"\u70b9\u51fb\u4e86\u89e3\u66f4\u591a\u5173\u4e8e[\u79d1\u5b66]\u7684\u6587\u7ae0\" target=\"_blank\">\u79d1\u5b66<\/a>\u57fa\u91d1\u59d4\u3001\u79d1\u6280\u90e8\u3001\u4e2d\u79d1\u9662\u548c<a href=\"https:\/\/www.cililun.com\/tag\/shang-hai\/\" title=\"\u70b9\u51fb\u4e86\u89e3\u66f4\u591a\u5173\u4e8e[\u4e0a\u6d77]\u7684\u6587\u7ae0\" target=\"_blank\">\u4e0a\u6d77<\/a>\u5e02\u7684\u8d44\u52a9\u3002<\/p>\n<p> <\/span><\/div>\n<\/p><\/div>\n<p><center><img\n<\/p>\n","protected":false},"excerpt":{"rendered":"<p>&nbsp;\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528\u8be5\u7c7b\u914d\u4f53\uff0c\u5728\u5916\u52a0Lewis\u78b1DMAP\u7684\u914d\u5408\u4e0b\uff0c\u6210\u529f\u5730\u5408\u6210\u4e86\u7b2c\u4e00\u4f8b\u7a00\u571f\u91d1\u5c5e\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269-\u94aa\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\uff08\u56fe1\uff0cA\uff09\uff0c\u5e76\u5bf9\u8fd9\u4e2a\u914d\u5408\u7269\u8fdb\u884c\u4e86X-\u5c04\u7ebf\u6676\u4f53\u7ed3\u6784\u7684\u8868\u5f81\u548cDFT\u7406\u8bba\u8ba1\u7b97\u3002\u6709\u5173\u7ed3\u679c\u4ee5\u5c01\u9762\u6587\u7ae0\u7684\u5f62\u5f0f\u53d1\u8868\u5728(Chem. Commun., 2010, 46, 4469)\u3002\u8fdb\u800c\u53c8\u8bbe\u8ba1\u4e86\u4e00\u4e2a\u65b0\u578b\u7684\u56db\u9f7f\u6c2e\u914d\u4f53\uff0c\u65e0\u9700\u5916\u52a0Lewis\u78b1\u5c31\u53ef\u4ee5\u5f97\u5230\u7a00\u571f\u91d1\u5c5e\u94aa\u672b\u7aef\u6c2e\u5361\u5bbe\u914d\u5408\u7269\uff08\u56fe1\uff0cB\uff09\u3002<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[137,174,123],"_links":{"self":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/posts\/2934"}],"collection":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/comments?post=2934"}],"version-history":[{"count":0,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/posts\/2934\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/media?parent=2934"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/categories?post=2934"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.cililun.com\/wp-json\/wp\/v2\/tags?post=2934"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}